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定電位電解におけるCu結晶(111)面転位位置の溶解の温度依存性
http://hdl.handle.net/10295/1064
http://hdl.handle.net/10295/106494675589-c3ca-4257-a625-ca7948fdb953
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
imas2.pdf (685.0 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||||||
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| 公開日 | 2008-08-25 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | 定電位電解におけるCu結晶(111)面転位位置の溶解の温度依存性 | |||||||||||||
| その他のタイトル | ||||||||||||||
| その他のタイトル | Temperature Dependence of Dissolution at Dislocations on the (111) Surface of Copper Crystal under Potentiastatic Electrolysis | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | jpn | |||||||||||||
| 主題 | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | 定電位電解 | |||||||||||||
| 主題 | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Cu結晶 | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | departmental bulletin paper | |||||||||||||
| 作成者 |
今清水, 雄二
× 今清水, 雄二
× 渡辺, 慈朗
× IMASHIMIZU, Yuji
× WATANABE, Jiro
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| 内容記述 | ||||||||||||||
| 内容記述タイプ | Other | |||||||||||||
| 内容記述 | The (111) surface of copper crystal was etched electrolytically under a constant overpotential of 143±10 mV in a solution containing 5 kmol'm-3 NaCI, 0.25 kmol'm-3 NaBr and 10-4 kmol'm-3 CuCI at different temperatures from 275 to 307 K. The depth and width of dislocation etch pits and the dissolved amount of a matrix surface were measured using optical and interference microscopes. From the variation of these quantities with an etching time, the vertical dissolution rate along a dislocation line, Vd, the lateral one, 1.>, and the vertical one of matrix surface, v" were determined. These dissolution rates showed a very different dependence on etching temperature. The value of log Vd increased steeply at a low temperature and then decreased gradually with an increase of temperature. The value of log v, increased more slowly at higher temperatures. On the other hand, log 1.> increased linearly with an increase of temperature. These temperature dependencies were discussed on the basis of the nucleation theory of crystal dissolution. |
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| 出版タイプ | ||||||||||||||
| 出版タイプ | VoR | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
| 書誌情報 |
秋田大学鉱山学部研究報告 巻 6, p. 83-89, 発行日 1985-10-22 |
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| ISSN | ||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 03898040 | |||||||||||||
| NCID | ||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AN00010307 | |||||||||||||
| 出版者 | ||||||||||||||
| 出版者 | 秋田大学鉱山学部 | |||||||||||||
