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Control of Structure of Oxide Cluster and the Application to Catalytic Technology
http://hdl.handle.net/10295/759
http://hdl.handle.net/10295/759d61471c6-a96c-449b-8dd9-36e0a8d162d3
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ijsmer10-2c.pdf (462.6 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||
|---|---|---|---|---|---|---|---|---|
| 公開日 | 2008-04-01 | |||||||
| タイトル | ||||||||
| タイトル | Control of Structure of Oxide Cluster and the Application to Catalytic Technology | |||||||
| 言語 | en | |||||||
| 言語 | ||||||||
| 言語 | eng | |||||||
| 主題 | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | Oxide | |||||||
| 主題 | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | Cluster | |||||||
| 主題 | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | Synthesis | |||||||
| 主題 | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | Selective oxidation | |||||||
| 主題 | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | Hydrocarbons | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
| 資源タイプ | journal article | |||||||
| アクセス権 | ||||||||
| アクセス権 | open access | |||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||
| 作成者 |
MIZUNO, Noritaka
× MIZUNO, Noritaka
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| 内容記述 | ||||||||
| 内容記述タイプ | Abstract | |||||||
| 内容記述 | The active sites for selective oxidation can be synthesized on polyoxometalates (oxide clusters). For example, Keggin-type di-iron-substitutedsilicotungstate, γ-SiW10{Fe(OH2)}2O38 6- ( I ), was synthesized by the reaction of the lacunary γ-SiW10O36 8- with Fe(NO3)3 in an acidic aqueous solution and isolated as the tetra-n-butylammonium salt (TBA-I). It was characterizedby various analyses and the structurewith the oxo-bridged di-iron site was clarified. TBA- I was stable and catalyzed selective oxidation of various alkanes and alkenes with hydrogen peroxide: Cyclohexane, adamantane, n-hexane, and n-pentane were catalytically oxidized. Even lower alkanes such as methane, ethane, propane, and n-butane were catalytically oxidized. It was remarkable that the efficiency of hydrogen peroxide utilizationto oxygenated products reached up to ca. 100% for the oxidation of cyclohexane and adamantane. Alkenes were mainly epoxidized with hydrogen peroxide. In addition, it was demonstrated that the TBA-1 showed high turnover numbers for the oxygenation of cyclohexane and epoxidation of alkenes with 1 atm oxygen. | |||||||
| 言語 | en | |||||||
| 出版タイプ | ||||||||
| 出版タイプ | VoR | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
| 書誌情報 |
en : International Journal of the Society of Materials Engineering for Resources 巻 10, 号 2, p. 135-137, 発行日 2002-09-01 |
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| 収録物識別子 | ||||||||
| 収録物識別子タイプ | ISSN | |||||||
| 収録物識別子 | 13479725 | |||||||
| 収録物識別子 | ||||||||
| 収録物識別子タイプ | NCID | |||||||
| 収録物識別子 | AA1095475X | |||||||
| 出版者 | ||||||||
| 出版者 | The Society of Materilas Engineering for resources of Japan | |||||||
| 言語 | en | |||||||
| 関連情報 | ||||||||
| 関連タイプ | isIdenticalTo | |||||||
| 識別子タイプ | DOI | |||||||
| 関連識別子 | https://doi.org/10.5188/ijsmer.10.135 | |||||||
