{"created":"2023-07-25T10:21:48.962607+00:00","id":963,"links":{},"metadata":{"_buckets":{"deposit":"974c864e-8f86-4652-ba26-19f6c6658095"},"_deposit":{"created_by":3,"id":"963","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"963"},"status":"published"},"_oai":{"id":"oai:air.repo.nii.ac.jp:00000963","sets":["590:664:671:683"]},"author_link":["3403"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002-09-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"137","bibliographicPageStart":"135","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"International Journal of the Society of Materials Engineering for Resources"}]}]},"item_10001_description_5":{"attribute_name":"内容記述（抄録）","attribute_value_mlt":[{"subitem_description":"The active sites for selective oxidation can be synthesized on polyoxometalates (oxide clusters). For example, Keggin-type di-iron-substitutedsilicotungstate, γ-SiW10{Fe(OH2)}2O38 6- ( I ), was synthesized by the reaction of the lacunary γ-SiW10O36 8- with Fe(NO3)3 in an acidic aqueous solution and isolated as the tetra-n-butylammonium salt (TBA-I). It was characterizedby various analyses and the structurewith the oxo-bridged di-iron site was clarified. TBA- I was stable and catalyzed selective oxidation of various alkanes and alkenes with hydrogen peroxide: Cyclohexane, adamantane, n-hexane, and n-pentane were catalytically oxidized. Even lower alkanes such as methane, ethane, propane, and n-butane were catalytically oxidized. It was remarkable that the efficiency of hydrogen peroxide utilizationto oxygenated products reached up to ca. 100% for the oxidation of cyclohexane and adamantane. Alkenes were mainly epoxidized with hydrogen peroxide. In addition, it was demonstrated that the TBA-1 showed high turnover numbers for the oxygenation of cyclohexane and epoxidation of alkenes with 1 atm oxygen.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Society of Materilas Engineering for resources of Japan"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.5188/ijsmer.10.135","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_25":{"attribute_name":"関連リンク","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.5188/ijsmer.10.135","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA1095475X","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"13479725","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"MIZUNO, Noritaka"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-16"}],"displaytype":"detail","filename":"ijsmer10-2c.pdf","filesize":[{"value":"462.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ijsmer10-2c.pdf","url":"https://air.repo.nii.ac.jp/record/963/files/ijsmer10-2c.pdf"},"version_id":"7a5b214e-f78e-4998-bb5a-e2664a6369c3"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Oxide","subitem_subject_scheme":"Other"},{"subitem_subject":"Cluster","subitem_subject_scheme":"Other"},{"subitem_subject":"Synthesis","subitem_subject_scheme":"Other"},{"subitem_subject":"Selective oxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydrocarbons","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Control of Structure of Oxide Cluster and the Application to Catalytic Technology","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Control of Structure of Oxide Cluster and the Application to Catalytic Technology"}]},"item_type_id":"10001","owner":"3","path":["683"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-04-01"},"publish_date":"2008-04-01","publish_status":"0","recid":"963","relation_version_is_last":true,"title":["Control of Structure of Oxide Cluster and the Application to Catalytic Technology"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-25T10:46:24.236132+00:00"}