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Synthesis and Guest Binding Properties of Regioselectively Anthranilate-Tosyl-Labeled β-Cyclodextrins
http://hdl.handle.net/10295/731
http://hdl.handle.net/10295/731ac4595f2-fc67-401d-ab58-1d71bf978ac9
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ijsmer11-2a.pdf (1.0 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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| 公開日 | 2008-03-14 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Synthesis and Guest Binding Properties of Regioselectively Anthranilate-Tosyl-Labeled β-Cyclodextrins | |||||||||||||
| 言語 | en | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| 主題 | ||||||||||||||
| 言語 | en | |||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Cyclodextrin | |||||||||||||
| 主題 | ||||||||||||||
| 言語 | en | |||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Anthranilate | |||||||||||||
| 主題 | ||||||||||||||
| 言語 | en | |||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Molecular sensing | |||||||||||||
| 主題 | ||||||||||||||
| 言語 | en | |||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Fluorescent sensor system | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| アクセス権 | ||||||||||||||
| アクセス権 | open access | |||||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||
| 作成者 |
KIKUCHI, Tohru
× KIKUCHI, Tohru
× DORJPALAM, Naranchimeg
× ENDO, Ken
× HAMADA, Fumio
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| 内容記述 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | Flexible hosts, regioselectively hetero-labeled 6A-anthranilate-6x-O-p-tosyl-labeled β-cyclodextrins (X=B or G, C or F, and D or E for β-1, β-2, and β-3, respectively), have been synthesized to investigate their chemo-sensor potential as host compounds for biochemical substances such as bile acids and terpenoids as guest molecules. These hosts showed pure monomer fluorescence, exhibiting increase in fluorescence intensity on complexation of the all guests examined. The extent of the fluorescence variation with a guest was employed to evaluate the sensing abilities of these hosts, and the sensing parameter (⊿I/I0) was used to describe the sensing abilities of the hosts. Hosts β-2 and β-3 recognized bile acids with high sensitivity, whereas β-1 detected all guests examined with low sensitivity. On the whole, the sequence of the binding ability of these hosts was β-3 > β-2 > β-1 for bile acids. The behaviors of the appended units of these hosts during a formation of the host-guest complexation were studied by induced circular dichroism (ICD) and fluorescence spectra. The ICD spectra of these hosts showed same patterns. The guest-induced variations in ICD and fluorescence spectra suggest that anthranilate and tosyl units take movement with a changing their mutual relationship in the place to work as spacers. The parameter values of the titled hosts are much higher than those of homo-labeled anthranilate β-cyclodextrin analogs. | |||||||||||||
| 言語 | en | |||||||||||||
| 出版タイプ | ||||||||||||||
| 出版タイプ | VoR | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
| 書誌情報 |
en : International Journal of the Society of Materials Engineering for Resources 巻 11, 号 2, p. 35-43, 発行日 2003-09-01 |
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| 収録物識別子 | ||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 13479725 | |||||||||||||
| 収録物識別子 | ||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AA1095475X | |||||||||||||
| 出版者 | ||||||||||||||
| 出版者 | The Society of Materilas Engineering for Resources of Japan | |||||||||||||
| 言語 | en | |||||||||||||
| 関連情報 | ||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | https://doi.org/10.5188/ijsmer.11.35 | |||||||||||||
