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  1. 30 理工学研究科・理工学部(含:旧鉱山・工学資源学部)
  2. 30A 学術誌論文
  3. 30A1 雑誌掲載論文

Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO4/Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates

http://hdl.handle.net/10295/00005794
http://hdl.handle.net/10295/00005794
d2790ff6-4c3d-4855-a6dc-e87bf6199a0b
名前 / ファイル ライセンス アクション
riA_2021_3.pdf riA_2021_3 (6.1 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2021-11-12
タイトル
タイトル Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO4/Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates
言語 en
言語
言語 eng
主題
主題Scheme Other
主題 lithium-ion battery
主題
主題Scheme Other
主題 degradation
主題
主題Scheme Other
主題 capacity fading
主題
主題Scheme Other
主題 electrochemical impedance spectroscopy
主題
主題Scheme Other
主題 LiFePO4
主題
主題Scheme Other
主題 graphite
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
作成者 Abe, Yusuke

× Abe, Yusuke

en Abe, Yusuke

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Hori, Natsuki

× Hori, Natsuki

en Hori, Natsuki

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Kumagai, Seiji

× Kumagai, Seiji

en Kumagai, Seiji

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内容記述
内容記述タイプ Abstract
内容記述 Lithium-ion batteries (LIBs) using a LiFePO4 cathode and graphite anode were assembled in coin cell form and subjected to 1000 charge-discharge cycles at 1, 2, and 5 C at 25 C. The performance degradation of the LIB cells under di erent C-rates was analyzed by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy. The most severe degradation occurred at 2 C while degradation was mitigated at the highest C-rate of 5 C. EIS data of the equivalent circuit model provided information on the changes in the internal resistance. The charge-transfer resistance within all the cells increased after the cycle test, with the cell cycled at 2 C presenting the greatest increment in the charge-transfer resistance. Agglomerates were observed on the graphite anodes of the cells cycled at 2 and 5 C; these were more abundantly produced in the former cell. The lower degradation of the cell cycled at 5 C was attributed to the lowered capacity utilization of the anode. The larger cell voltage drop caused by the increased C-rate reduced the electrode potential variation allocated to the net electrochemical reactions, contributing to the charge-discharge specific capacity of the cells.
言語 en
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
書誌情報 Energies

巻 12, 号 23, p. 4507, 発行日 2019
収録物識別子
収録物識別子タイプ ISSN
収録物識別子 1996-1073
出版者
出版者 MDPI
関連情報
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 https://doi.org/10.3390/en12234507
権利情報
権利情報 © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
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