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Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO4/Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates
http://hdl.handle.net/10295/00005794
http://hdl.handle.net/10295/00005794d2790ff6-4c3d-4855-a6dc-e87bf6199a0b
名前 / ファイル | ライセンス | アクション |
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riA_2021_3 (6.1 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2021-11-12 | |||||
タイトル | ||||||
タイトル | Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO4/Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
主題 | ||||||
主題Scheme | Other | |||||
主題 | lithium-ion battery | |||||
主題 | ||||||
主題Scheme | Other | |||||
主題 | degradation | |||||
主題 | ||||||
主題Scheme | Other | |||||
主題 | capacity fading | |||||
主題 | ||||||
主題Scheme | Other | |||||
主題 | electrochemical impedance spectroscopy | |||||
主題 | ||||||
主題Scheme | Other | |||||
主題 | LiFePO4 | |||||
主題 | ||||||
主題Scheme | Other | |||||
主題 | graphite | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
作成者 |
Abe, Yusuke
× Abe, Yusuke× Hori, Natsuki× Kumagai, Seiji |
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内容記述 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Lithium-ion batteries (LIBs) using a LiFePO4 cathode and graphite anode were assembled in coin cell form and subjected to 1000 charge-discharge cycles at 1, 2, and 5 C at 25 C. The performance degradation of the LIB cells under di erent C-rates was analyzed by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy. The most severe degradation occurred at 2 C while degradation was mitigated at the highest C-rate of 5 C. EIS data of the equivalent circuit model provided information on the changes in the internal resistance. The charge-transfer resistance within all the cells increased after the cycle test, with the cell cycled at 2 C presenting the greatest increment in the charge-transfer resistance. Agglomerates were observed on the graphite anodes of the cells cycled at 2 and 5 C; these were more abundantly produced in the former cell. The lower degradation of the cell cycled at 5 C was attributed to the lowered capacity utilization of the anode. The larger cell voltage drop caused by the increased C-rate reduced the electrode potential variation allocated to the net electrochemical reactions, contributing to the charge-discharge specific capacity of the cells. | |||||
言語 | en | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
書誌情報 |
Energies 巻 12, 号 23, p. 4507, 発行日 2019 |
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収録物識別子 | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1996-1073 | |||||
出版者 | ||||||
出版者 | MDPI | |||||
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関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.3390/en12234507 | |||||
権利情報 | ||||||
権利情報 | © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |