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準可逆性電極の電解における電流密度・過電圧曲線の解析
http://hdl.handle.net/10295/1063
http://hdl.handle.net/10295/1063d361457d-7453-4241-bfd6-c7f6cfdb569a
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
imas1.pdf (600.5 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2008-08-25 | |||||
| タイトル | ||||||
| タイトル | 準可逆性電極の電解における電流密度・過電圧曲線の解析 | |||||
| その他のタイトル | ||||||
| その他のタイトル | An Analysis of Current Density-Overpotential Curve for Quasi-reversible Electrode System | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| 主題 | ||||||
| 主題Scheme | Other | |||||
| 主題 | 準可逆性電極 | |||||
| 主題 | ||||||
| 主題Scheme | Other | |||||
| 主題 | 電流密度 | |||||
| 主題 | ||||||
| 主題Scheme | Other | |||||
| 主題 | 電解 | |||||
| 主題 | ||||||
| 主題Scheme | Other | |||||
| 主題 | 過電圧曲線 | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 作成者 |
今清水, 雄二
× 今清水, 雄二× IMASHIMIZU, Yuji |
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| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | It has been considered that the analysis of the current density-overpotential curve for the quasireversible electrode system would be complicated, while that for the reversible and irreversible ones could be done approximately by using the reduced forms of the general expression which represents the steady-state current flowing at the electrode under an overpotential. In this report, it is shown that if the anodic and cathodic diffusion-limited current densities were given for a quasi-reversible electrode system by some proper method, the activation and concentration overpotentials under a polarization of the electrode could be determined so that the current densityoverpotential curve would be analyzed explicitly by the general expression, resulting in the estimation of the exchange current density and the transfer coefficient. This approach is applied to analyze the current density-overpotential curve for an anodic dissolution of the (111) surface of copper single crystal in a concentrated solution ofNaCI containing NaBr and a small amount ofCuCl, and proved reasonable. |
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| 出版タイプ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 書誌情報 |
秋田大学工学資源学部研究報告 en : Scientific and technical reports of Faculty of Engineering and Resource Science, Akita University 巻 19, p. 19-24, 発行日 1998-10-31 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 13457241 | |||||
| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11410906 | |||||
| 出版者 | ||||||
| 出版者 | 秋田大学工学資源学部 | |||||
