@article{oai:air.repo.nii.ac.jp:00000904, author = {KONDO, Yoshihiko and HAMADA, Fumio}, issue = {2}, journal = {International Journal of the Society of Materials Engineering for Resources}, month = {Mar}, note = {It is well known that p-tert-butylthiacalixarenes can make host-guest complexation with organic guest molecules and metal cations. In order to study crystal structural properties of the host molecule with organic compounds, we tried to make a new crystal of the p-terf-butylthiacalix [6] arene with benzylamine. Treatment of thiacalix [6] arene with excess of benzylamine afforded the complex of thiacalix [6] arene with 8 molecules of benzylamine as crystals, which shows highly-extensive hydrogen bonded between host and guests to give rise to supramolecular assembly. The structure of thiacalix [6] arene as a host is 1,2,3-alternate with 4 molecules benzylamine as inner guests and the other 4 molecules of benzylamine locate outside of thiacalix [6] arene.}, pages = {60--63}, title = {Supramolecular assembly of p-tert-butylthiacalix[6]arene with benzylamine complex based on hydrogen bond}, volume = {13}, year = {2006} }