{"created":"2023-07-25T10:21:43.085716+00:00","id":828,"links":{},"metadata":{"_buckets":{"deposit":"1d53b562-6e94-47a1-8098-2dd3707eb82b"},"_deposit":{"created_by":15,"id":"828","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"828"},"status":"published"},"_oai":{"id":"oai:air.repo.nii.ac.jp:00000828","sets":["590:664:665:667"]},"author_link":[],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-06-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"41","bibliographicPageStart":"39","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"素材物性学雑誌","bibliographic_titleLang":"ja"}]}]},"item_10001_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本素材物性学会","subitem_publisher_language":"ja"}]},"item_10001_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1724099666130":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"0919-9853","subitem_source_identifier_type":"PISSN"},{"subitem_source_identifier":"AN10140273","subitem_source_identifier_type":"NCID"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"作成者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"加藤, 治雄","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"伊藤, 優","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"米澤, 節子","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"本田, 克美","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"荒井, 康彦","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"KATO, Haruo","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"ITO, Yu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"YONEZAWA, Setsuko","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"HONDA, Katsumi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"ARAI, Yasuhiko","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-16"}],"displaytype":"detail","filename":"sozai17-2c.pdf","filesize":[{"value":"445.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"sozai17-2c.pdf","url":"https://air.repo.nii.ac.jp/record/828/files/sozai17-2c.pdf"},"version_id":"f4aeaf25-8755-497a-bd70-ec0f3d305341"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Diels-Alder reaction","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"reaction rate constant","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"mixed solvent","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"excess activation energy","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"混合溶媒中のイソプレンと無水マレイン酸の反応速度定数の相関","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"混合溶媒中のイソプレンと無水マレイン酸の反応速度定数の相関","subitem_title_language":"ja"},{"subitem_title":"Correlation of Reaction Rate Constants for Isoprene and Maleic Anhydride in Mixed Solvents","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"15","path":["667"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-03-05"},"publish_date":"2008-03-05","publish_status":"0","recid":"828","relation_version_is_last":true,"title":["混合溶媒中のイソプレンと無水マレイン酸の反応速度定数の相関"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2024-08-25T18:12:23.688924+00:00"}