{"created":"2023-07-25T10:21:27.480694+00:00","id":466,"links":{},"metadata":{"_buckets":{"deposit":"6a803b3d-2430-43b5-9678-7e300c15d4b5"},"_deposit":{"created_by":3,"id":"466","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"466"},"status":"published"},"_oai":{"id":"oai:air.repo.nii.ac.jp:00000466","sets":["590:591:592:593"]},"author_link":["1298","1294","1296","1295","1299","1297"],"item_10002_alternative_title_34":{"attribute_name":"別タイトル","attribute_value_mlt":[{"subitem_alternative_title":"＜Original Papers＞Studies on Characterization of Acid Properties and Application to Catalysis of Chemically Modified Natural Clinoptilolite"}]},"item_10002_biblio_info_36":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002-10-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"22","bibliographicPageStart":"13","bibliographicVolumeNumber":"23","bibliographic_titles":[{"bibliographic_title":"秋田大学工学資源学部 研究報告"}]}]},"item_10002_description_29":{"attribute_name":"内容記述（抄録）","attribute_value_mlt":[{"subitem_description":"From the viewpoint of effective utilization of natural sedimentary zeolite, clinoptilolite (CZ), produced at Futatsui, Akita Prefecture, characterization of solid acid properties and catalytic reaction tests have been made. The acid properties of CZs exchanged with alkali and alkali earth cation and the samples chemically treated with hydrochloric acid in various concentrations were analyzed by micro-calorimetry of NH_3 adsorption at 473K. The reaction rate on the decomposition of tert-butyl acetate (TBA) over CZs was proportional to the add strength. On the skeletal isomerization reaction of cyclohexene into methylcyclopentenes (MCP) were catalyzed over CZs. 1,4-Dihydropyridines (DHP) were oxidized to corresponding pyridines with H_2O2 aqueous solution over CZ-Mg. The acid ester decomposition of 3,5-di-tert-butoxy-carbonyl pyridine into 3,5-pyridinecarboxylic acid without any solvents proceeded effectively using CZ-Mg at 443K. This paper deals with environmentally benign protocols using CZs based on the Green Sustainable Chemistry (GSC).","subitem_description_type":"Other"}]},"item_10002_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"秋田大学工学資源学部"}]},"item_10002_source_id_27":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"13457241","subitem_source_identifier_type":"ISSN"}]},"item_10002_source_id_35":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA11410906","subitem_source_identifier_type":"NCID"}]},"item_10002_text_25":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"秋田大学工学資源学部"},{"subitem_text_value":"秋田大学教育文化学部"},{"subitem_text_value":"鳥取大学"}]},"item_10002_version_type_37":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"野村, 正幸"}],"nameIdentifiers":[{"nameIdentifier":"1294","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"佐藤, 寛次"}],"nameIdentifiers":[{"nameIdentifier":"1295","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中村, 宗和[他]"}],"nameIdentifiers":[{"nameIdentifier":"1296","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"NOMURA, Masayuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1297","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"SATOH, Kanji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1298","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"NAKAMURA, Munekazu[et al]","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"1299","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-16"}],"displaytype":"detail","filename":"KJ00000048346.pdf","filesize":[{"value":"959.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00000048346.pdf","url":"https://air.repo.nii.ac.jp/record/466/files/KJ00000048346.pdf"},"version_id":"65f217f1-c082-4d9e-8cf5-44903b72978c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"＜論文＞化学修飾天然クリノプチロライトの固体酸特性解析と触媒への応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"＜論文＞化学修飾天然クリノプチロライトの固体酸特性解析と触媒への応用"}]},"item_type_id":"10002","owner":"3","path":["593"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-12-14"},"publish_date":"2007-12-14","publish_status":"0","recid":"466","relation_version_is_last":true,"title":["＜論文＞化学修飾天然クリノプチロライトの固体酸特性解析と触媒への応用"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-25T12:08:22.751468+00:00"}