| Item type |
紀要論文 / Departmental Bulletin Paper(1) |
| 公開日 |
2007-12-14 |
| タイトル |
|
|
タイトル |
＜論文＞化学修飾天然クリノプチロライトの固体酸特性解析と触媒への応用 |
| その他のタイトル |
|
|
その他のタイトル |
＜Original Papers＞Studies on Characterization of Acid Properties and Application to Catalysis of Chemically Modified Natural Clinoptilolite |
| 言語 |
|
|
言語 |
jpn |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
departmental bulletin paper |
| 作成者 |
野村, 正幸
佐藤, 寛次
中村, 宗和[他]
NOMURA, Masayuki
SATOH, Kanji
NAKAMURA, Munekazu[et al]
|
| 内容記述 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
From the viewpoint of effective utilization of natural sedimentary zeolite, clinoptilolite (CZ), produced at Futatsui, Akita Prefecture, characterization of solid acid properties and catalytic reaction tests have been made. The acid properties of CZs exchanged with alkali and alkali earth cation and the samples chemically treated with hydrochloric acid in various concentrations were analyzed by micro-calorimetry of NH_3 adsorption at 473K. The reaction rate on the decomposition of tert-butyl acetate (TBA) over CZs was proportional to the add strength. On the skeletal isomerization reaction of cyclohexene into methylcyclopentenes (MCP) were catalyzed over CZs. 1,4-Dihydropyridines (DHP) were oxidized to corresponding pyridines with H_2O2 aqueous solution over CZ-Mg. The acid ester decomposition of 3,5-di-tert-butoxy-carbonyl pyridine into 3,5-pyridinecarboxylic acid without any solvents proceeded effectively using CZ-Mg at 443K. This paper deals with environmentally benign protocols using CZs based on the Green Sustainable Chemistry (GSC). |
| 出版タイプ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| 書誌情報 |
秋田大学工学資源学部 研究報告
巻 23,
p. 13-22,
発行日 2002-10-31
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
13457241 |
| NCID |
|
|
収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA11410906 |
| 出版者 |
|
|
出版者 |
秋田大学工学資源学部 |
KJ00000048346.pdf (959.0 kB)
