{"created":"2023-07-25T10:22:13.663670+00:00","id":1523,"links":{},"metadata":{"_buckets":{"deposit":"7fae5938-325c-4f23-8b50-6759c4c192ed"},"_deposit":{"created_by":3,"id":"1523","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"1523"},"status":"published"},"_oai":{"id":"oai:air.repo.nii.ac.jp:00001523","sets":["590:591:592:860"]},"author_link":["5515","5513","5512","5514"],"item_10002_alternative_title_34":{"attribute_name":"別タイトル","attribute_value_mlt":[{"subitem_alternative_title":"Studies on Two-Dimensional ¹H-NMR and Absorption Spectra of Anthranilate Moieties in Modified β- and γ-Cyclodextrins"}]},"item_10002_biblio_info_36":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1999-10-29","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"20","bibliographicPageStart":"15","bibliographicVolumeNumber":"20","bibliographic_titles":[{"bibliographic_title":"秋田大学工学資源学部研究報告"},{"bibliographic_title":"Scientific and technical reports of Faculty of Engineering and Resource Science,Akita University","bibliographic_titleLang":"en"}]}]},"item_10002_description_29":{"attribute_name":"内容記述（抄録）","attribute_value_mlt":[{"subitem_description":"Two-dimensional ¹H-NMR spectra (2D-¹H-NMR) of 6A,6B-; 6A,6c-; and 6A,6D-bis anthranilate  β-cyclodextrins (β-1, β-2, and β-3, respectively) and 6A,6B-; 6A,6c-; 6A,6D-; and 6A,6E-bis anthranilate γ-cyclodextrins (γ-1, γ-2, γ-3, and γ-4, respectively) have been measured to consider the interaction of two anthranilate moieties. 2D-¹H-NMR of those compounds obtained by H-H cosy method indicated that the interaction of two appended moieties is interacted each other, because 2D-¹H-NMR of those hosts showed that degree of overlap of two appended moieties was extended in the order β-1>β-2>β-3 and γ-1>γ-2>γ-3>γ-4. It suggests that two appended moieties depended on how much far away each other can move easily toward inside or outside of cavity of cyclodextrin. The UV-Vis spectra of those hosts with the guest such as bile acid are changed with isosbestic points. The results obtained from 2D-¹H-NMR and UV-Vis spectra describe that the binding mechanism of those hosts are undergoing with induced-fit type of host-guest complexes.","subitem_description_type":"Other"}]},"item_10002_publisher_30":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"秋田大学工学資源学部"}]},"item_10002_source_id_27":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"13457241","subitem_source_identifier_type":"ISSN"}]},"item_10002_source_id_35":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA11410906","subitem_source_identifier_type":"NCID"}]},"item_10002_version_type_37":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"成田, 美雪"}],"nameIdentifiers":[{"nameIdentifier":"5512","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"濱田, 文男"}],"nameIdentifiers":[{"nameIdentifier":"5513","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"NARITA, Miyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5514","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"HAMADA, Fumio","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5515","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-16"}],"displaytype":"detail","filename":"koushi20a.pdf","filesize":[{"value":"572.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"koushi20a.pdf","url":"https://air.repo.nii.ac.jp/record/1523/files/koushi20a.pdf"},"version_id":"33b53ab4-75cb-474c-9d57-65d34aa37c6a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"シクロデキストリン","subitem_subject_scheme":"Other"},{"subitem_subject":"アントラニル酸","subitem_subject_scheme":"Other"},{"subitem_subject":"二次元1H-NMR","subitem_subject_scheme":"Other"},{"subitem_subject":"吸収スペクトル","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"2置換β-およびγ-シクロデキストリンにおけるアントラニル酸修飾残基の二次元¹H-NMRおよび吸収スペクトル挙動","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"2置換β-およびγ-シクロデキストリンにおけるアントラニル酸修飾残基の二次元¹H-NMRおよび吸収スペクトル挙動"}]},"item_type_id":"10002","owner":"3","path":["860"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-12-26"},"publish_date":"2008-12-26","publish_status":"0","recid":"1523","relation_version_is_last":true,"title":["2置換β-およびγ-シクロデキストリンにおけるアントラニル酸修飾残基の二次元¹H-NMRおよび吸収スペクトル挙動"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-25T11:18:11.984699+00:00"}