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NaCl-KCl-Li_2MoO_4溶融塩中におけるMoの電解析出挙動
http://hdl.handle.net/10295/1259
http://hdl.handle.net/10295/1259aabda336-7f47-4a55-9162-0477063a1990
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
sozai14-4.pdf (940.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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| 公開日 | 2008-10-27 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | NaCl-KCl-Li_2MoO_4溶融塩中におけるMoの電解析出挙動 | |||||||||||||
| 言語 | ja | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Electrolytic Deposition Behavior of Mo in Molten NaCl-KCl-Li_2MoO_4 | |||||||||||||
| 言語 | en | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | jpn | |||||||||||||
| 主題 | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Electrolytic Deposition | |||||||||||||
| 主題 | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Molten Salt | |||||||||||||
| 主題 | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Molybdenum | |||||||||||||
| 主題 | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Sodium Chloride-Potassium Chloride | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| アクセス権 | ||||||||||||||
| アクセス権 | open access | |||||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||
| 作成者 |
土田, 知行
× 土田, 知行
× 原, 基
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| 内容記述 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | The electrolytic deposition behavior of Mo in molten salt has been studied using the equimolar NaCI-KCI molten salt, which contains Li,MoO, as a molybdenum source. In the equimolar NaCIKCI molten salt containing only Li2MoO" a high cathodic current corresponding to the reduction reaction of Li2MoO, was observed under cathodic polarization. Under this polarization, the deposition of Mo could not be observed, but the deposition of Li,Mo20, which grew perpendicular to the substrate surface was observed. On the other hand, in the equimolar NaCI-KCI molten salt containing B20 3, AIF3 or K2SiF6 as the second addition agents in addition to the Li2MoO" a higher cathodic current was observed under cathodic polarization, showing that the cathodic reaction was more active. Under the cathodic polarization in the molten salt containing B,O, or AIF3 as the second addition agent, the deposition of Mo02 occurred without depending on the polarization potential. On the contrary, under the cathodic polarization in the molten salt containing K2SiF6 as the second addition agent the deposition material was changed with the polarization potential. Thus, in the molten salt containing K2SiF6, MoO, was deposited at high potentials, while Mo was deposited at low potentials. Consequently, it was found that in the equimolar NaCI-KCI molten salt containing Li2MoO, and K2SiF6, Mo was deposited under the cathodic polarization at low potential | |||||||||||||
| 言語 | en | |||||||||||||
| 出版タイプ | ||||||||||||||
| 出版タイプ | VoR | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
| 書誌情報 |
素材物性学雑誌 巻 14, 号 1/2, p. 20-28, 発行日 2001-12-01 |
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| 収録物識別子 | ||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 09199853 | |||||||||||||
| 収録物識別子 | ||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AN10140273 | |||||||||||||
| 出版者 | ||||||||||||||
| 出版者 | 日本素材物性学会 | |||||||||||||
