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混合溶媒中のイソプレンと無水マレイン酸の反応速度定数の相関
http://hdl.handle.net/10295/602
http://hdl.handle.net/10295/602095e738d-3df4-4f36-9477-44d5e764313e
名前 / ファイル | ライセンス | アクション |
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sozai17-2c.pdf (445.2 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-03-05 | |||||
タイトル | ||||||
タイトル | 混合溶媒中のイソプレンと無水マレイン酸の反応速度定数の相関 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Diels-Alder reaction | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | reaction rate constant | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | mixed solvent | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | excess activation energy | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
別タイトル | ||||||
その他のタイトル | Correlation of Reaction Rate Constants for Isoprene and Maleic Anhydride in Mixed Solvents | |||||
著者 |
加藤, 治雄
× 加藤, 治雄× 伊藤, 優× 米澤, 節子× 本田, 克美× 荒井, 康彦× KATO, Haruo× ITO, Yu× YONEZAWA, Setsuko× HONDA, Katsumi× ARAI, Yasuhiko |
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内容記述(抄録) | ||||||
内容記述タイプ | Other | |||||
内容記述 | A correlative method for determination of reaction rate constants in mixed solvents system previously proposed was applied for Diels-Alder reaction of isoprene-maleic anhydride. In this study, several binary mixed solvents such as hexane, toluene, ethyl acetate and monochlorobenzene with nitrobenzene were examined. By adjusting the model parameters for the excess activation energy, the relationship between rate constants and compositions of mixed solvents used were well explained. The excess activation energy was compared with the excess Gibbs energy predicted by an activity-coefficient equation. | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
書誌情報 |
日本素材物性学雑誌 巻 17, 号 2, p. 39-41, 発行日 2004-06-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09199853 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN10140273 | |||||
出版者 | ||||||
出版者 | 日本素材物性学会 |