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The resultant carbonaceous residues were\nactivated in a stream of CO2 at 1173 K for 1 h. Adsorption of N2 at 77 K was measured to\ninvestigate the pore structure and the surface properties of the pyrolyzed and activated materials\nfrom the cedar bark. Both specific surface areas and total pore volumes of the materials pyrolyzed\nat temperatures below 573 K were small, indicating that pore structures were not developed under\nmild conditions. However, those of the samples heated at 673 K increased with increasing time of\nthe treatment, during which micro porosity was mainly developed. Activation of the pyrolyzed\ncedar bark led to drastic increase in specific surface area and pore volume. The increase was due to\nthe selective formation of the micro pores which distributed mainly less than 0.35 nm in radius.\nAnalytical results of adsorption data using t-plot and a ,-plot and IR spectra methods suggest\nthat the surface properties of both pyrolyzed and activated cedar bark are different from those of\ntypical carbon black. 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スギ樹皮の熱分解物と活性炭の細孔特性
http://hdl.handle.net/10295/1271
http://hdl.handle.net/10295/12715df7e450-3dad-4873-8d45-fd4831397c01
名前 / ファイル | ライセンス | アクション |
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sozai15b3.pdf (631.9 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-10-28 | |||||
タイトル | ||||||
タイトル | スギ樹皮の熱分解物と活性炭の細孔特性 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Japanese cedar bark | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Adsorption characteristics | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Pyrolyzed cedar bark | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Activated carbon | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | N2 adsorption | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
別タイトル | ||||||
その他のタイトル | Characteristics of Pyrolyzed and Activated Carbonaceous Materials From Japanese Cedar Bark | |||||
著者 |
進藤, 隆世志
× 進藤, 隆世志× 平川, 義典× 工藤, 宏隆× 北林, 茂明× 小沢, 泉太郎× SHINDO, Takayoshi× HIRAKAWA, Yoshinori× KUDO, Hirotaka× KITABAYASHI, Shigeaki× OZAWA, Sentaro |
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内容記述(抄録) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Abstract Japanese cedar (Cryptomeriajaponica D, Don) bark was pyrolyzed in a stream of N, at 473-673 K for 3-12 h under atmospheric pressure. The resultant carbonaceous residues were activated in a stream of CO2 at 1173 K for 1 h. Adsorption of N2 at 77 K was measured to investigate the pore structure and the surface properties of the pyrolyzed and activated materials from the cedar bark. Both specific surface areas and total pore volumes of the materials pyrolyzed at temperatures below 573 K were small, indicating that pore structures were not developed under mild conditions. However, those of the samples heated at 673 K increased with increasing time of the treatment, during which micro porosity was mainly developed. Activation of the pyrolyzed cedar bark led to drastic increase in specific surface area and pore volume. The increase was due to the selective formation of the micro pores which distributed mainly less than 0.35 nm in radius. Analytical results of adsorption data using t-plot and a ,-plot and IR spectra methods suggest that the surface properties of both pyrolyzed and activated cedar bark are different from those of typical carbon black. It is indicated that organic moiety and oxygenated functional groups originated from cedar bark may affect the surface characteristics of pyrolyzed and activated cedar bark. |
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著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
書誌情報 |
素材物性学雑誌 巻 15, 号 2, p. 43-48, 発行日 2002-12-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09199853 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN10140273 | |||||
出版者 | ||||||
出版者 | 日本素材物性学会 |